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Cyanogen Azidodithiocarbonate

Cyanogen azidodithiocarbonate is insensitive to impact and is much more stable than azidocarbondisulfide. On expln by heat it develops a dk orn vapor comparable in odor to thiocyahogen and to cyanogen thiocyanate. [Pg.636]

When a current of NHS gas is brought into contact with the dry solid compd, expl decompn occurs immedy. Bubbled through an ethereal soln of the CN salt, NHS gas ppts a wh solid consisting chiefly of NH azidodithiocarbonate. The CN salt and coned H2S04 react with explosive violence. Other dil acids react more slowly, than coned acids but all eventually effect soln of cyanogen azidodithiocarbonate... [Pg.636]

Cyanogen Azidodithiocarbonate, NC SCSNs, mw 144.19, N 38.86% wh crysts, stable at 0° a iarge sample explodes at 65-70° a smaii sample becomes yel at 60° and at 81° fusion jflVpc pl cc, with compn and formation of yel-orn residue very si sol in w, CC14 or CSj, sol in most org solvs, especially acet or ethyl acetate at 0°. It is formed by the... [Pg.635]

Cyanogen Azidodithiocarbonate A635-R Cyanomethane. See Acetonitrile A45-L Cyclotrimethyleneimine. See Azetidine A519-L... [Pg.680]

See other pages where Cyanogen Azidodithiocarbonate is mentioned: [Pg.635]    [Pg.368]    [Pg.636]    [Pg.367]    [Pg.636]    [Pg.636]    [Pg.636]    [Pg.635]    [Pg.368]    [Pg.636]    [Pg.367]    [Pg.636]    [Pg.636]    [Pg.636]   
See also in sourсe #XX -- [ Pg.635 ]

See also in sourсe #XX -- [ Pg.635 ]



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