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Cyano-bridged metal complex

A photoinduced phase transition has been observed in several cyano-bridged metal complexes [39]. They exhibit bistable electronic states at room temperature. The energy barrier between these bistable states maintains a photoproduced state even after photo-irradiation is terminated. Also, the state can easily be reset either via optical irradiation or temperature control. Moreover, typical phase transitions are excited in a cascaded manner, meaning that they exhibit high quantum efficiencies. [Pg.73]

Ethynyl- and ethenyl-Co111 corrins form a and n complexes respectively with Ag1, and cyano Co111 (Con) complexes coordinate metal cyanide via a CN bridge, i.e. M(CN)5 —CN-Co(Con)CN (M = Fe111, Fe11, Co111). [Pg.884]

Figure 9.18 Variable temperatnre (4—82 K) susceptibility for ErMn [99]. (With kind permission from Springer Science+Business Media Transition Metal Chemistry The magnetochemistry of novel cyano-bridged complexes Ln(DMF)4(H20)2Mn (CN)6-H20 (Ln = Tb, Dy, Er), 26, 2001, 287-289, B. Yan, and Z. Chen.)... Figure 9.18 Variable temperatnre (4—82 K) susceptibility for ErMn [99]. (With kind permission from Springer Science+Business Media Transition Metal Chemistry The magnetochemistry of novel cyano-bridged complexes Ln(DMF)4(H20)2Mn (CN)6-H20 (Ln = Tb, Dy, Er), 26, 2001, 287-289, B. Yan, and Z. Chen.)...
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Cyano bridging

Cyano complexes

Cyano-bridged complexes

Cyano-metal complexes

Metal bridged

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