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Cyanides Michael donors

The mechanism of the cyanide- and thioazolium ion-catalyzed conjugate addition reactions is considered to be analogous to the Lapworth mechanism for the cyanide-catalyzed benzoin condensation. Thus the cyano-stabilized carbanion resulting from deprotonation of the cyanohydrin of the aldehyde is presumed to be the actual Michael donor. After conjugate addition to the activated olefin, cyanide is eliminated to form the product and regenerate the catalyst. [Pg.165]


See other pages where Cyanides Michael donors is mentioned: [Pg.35]    [Pg.259]    [Pg.341]   
See also in sourсe #XX -- [ Pg.259 ]

See also in sourсe #XX -- [ Pg.4 , Pg.259 ]

See also in sourсe #XX -- [ Pg.4 , Pg.259 ]




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Michael donor

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