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Cumarol alcohol

The network structure of lignin, which is made of phenol units, coagulates the cell wall in wood tissue, which is composed of cellulose and hemicellulose. Lignin is currently a waste product because of its complicated structure [1-4], It is produced by an oxidative polymerization of coniferyl alcohol, sinapil alcohol, and cumarol alcohol (Figure 1) catalyzed by metalloenzymes such as laccase and peroxidases. Laccase is a protein whose active center contains four coppers per one subunit [5-20],... [Pg.536]

Figure 8 presents a selected part of a gas chromatogram recorded for the extracts A and B. The extract B consisting of furan derivative contains more oxygen heterocyclic compounds compared to extract A. The excess of 0-heterocycles is responsible for the observed (better) antioxidant activity of extract B (Figure 9). Careful analysis of GC, FT-IR, and NMR results let to identify more than 50 compounds which conld be accounted to the compounds potentially exhibiting antioxidant activity. Some of them are listed in Table 3 which contains names, formulas and information on most typical MS ions observed during the GC-MS identification. In general, most of the identified compounds may be seen as derivatives of the three basic structures (Figure 10) (A) cumarol alcohol, (B) coniferyl alcohol, and (C) synapine alcohol. Figure 8 presents a selected part of a gas chromatogram recorded for the extracts A and B. The extract B consisting of furan derivative contains more oxygen heterocyclic compounds compared to extract A. The excess of 0-heterocycles is responsible for the observed (better) antioxidant activity of extract B (Figure 9). Careful analysis of GC, FT-IR, and NMR results let to identify more than 50 compounds which conld be accounted to the compounds potentially exhibiting antioxidant activity. Some of them are listed in Table 3 which contains names, formulas and information on most typical MS ions observed during the GC-MS identification. In general, most of the identified compounds may be seen as derivatives of the three basic structures (Figure 10) (A) cumarol alcohol, (B) coniferyl alcohol, and (C) synapine alcohol.

See also in sourсe #XX -- [ Pg.536 ]




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