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Crystal structure boron trifluoride complexes

It is especially important to investigate the molecular structure of coordination compounds in the vapor phase because the relatively weak coordination interactions may be considerably influenced by intermolecular interactions in solutions and especially in crystals. It has been shown that the geometrical variations can be correlated with other properties of the molecular complexes ). In particular the structural changes in the F3B N(CH3)3 and CI3B N(CH3)3 molecules ) relative to the respective monomeric species unambiguously indicated boron trichloride to be a stronger acceptor than boron trifluoride. Data on the geometry and force field have also been correlated ). [Pg.58]


See other pages where Crystal structure boron trifluoride complexes is mentioned: [Pg.1071]    [Pg.116]   


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Boron complexes

Boron crystal structures

Boron crystallization

Boron structure

Boron trifluoride

Boron trifluoride crystal structure

Boronates structure

Boronic structure

Complexes boron trifluoride

Trifluoride, structure

Trifluorides, structures

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