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Cryptands conformational rigidity

Thermodynamic behaviour of the complexes should be differentiated from their kinetic behaviour. For instance, conformationally most rigid cryptands form their complexes very slowly. [Pg.54]

In this chapter, the synthesis and properties of two further categories of synthetic macrocyclic ligand types, exhibiting different degrees of restricted conformational flexibihty, are discussed. These are the rigid spherands and the somewhat more flexible but stiU sterically restrained bi- or tricyclic cryptand ligands. [Pg.784]

See other pages where Cryptands conformational rigidity is mentioned: [Pg.117]    [Pg.100]    [Pg.3293]    [Pg.1109]    [Pg.68]    [Pg.74]    [Pg.94]    [Pg.297]    [Pg.748]    [Pg.170]    [Pg.53]    [Pg.54]    [Pg.748]    [Pg.923]    [Pg.937]    [Pg.176]    [Pg.57]    [Pg.380]    [Pg.68]    [Pg.74]    [Pg.94]    [Pg.297]    [Pg.5071]    [Pg.748]    [Pg.52]    [Pg.3]    [Pg.23]    [Pg.346]    [Pg.5070]    [Pg.1569]    [Pg.1583]    [Pg.1892]    [Pg.1893]    [Pg.217]    [Pg.267]    [Pg.778]    [Pg.42]    [Pg.789]    [Pg.791]    [Pg.974]    [Pg.150]   
See also in sourсe #XX -- [ Pg.53 ]

See also in sourсe #XX -- [ Pg.3 , Pg.53 ]



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Cryptands 2.1.1 [cryptand

Cryptands, conformers

Rigid conformation

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