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Cross cycloalkanones

The selective dimerization of aldehydes to esters [236] as well as the cross-condensation of cycloalkanones with aldehydes and primary alcohols [237] were found to proceed very efficiently under mild conditions with 1 as catalyst (Scheme 8-33). [Pg.273]

For Aldol and Related Reactions. The TMSI/(TMS)2NH combination can be used for the synthesis of polycyclic cyclobutane derivatives by tandem intramolecular Michael-aldol reaction. TMSI-induced diastereoselective synthesis of tetrahy-dropyranones by a tandem Knoevenagel-Michael reaction, has also been developed. More recently, the facile synthesis of a,a bis(substituted benzylidene)cycloalkanones has been reported, using TMSI (in situ generated) mediated cross-aldol condensations (eq 53). ... [Pg.331]

See other pages where Cross cycloalkanones is mentioned: [Pg.378]    [Pg.365]    [Pg.382]    [Pg.200]    [Pg.156]    [Pg.954]    [Pg.954]    [Pg.957]    [Pg.1169]    [Pg.365]   
See also in sourсe #XX -- [ Pg.619 ]



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Cycloalkanone

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