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Cross-coupling reactions alkynylmetals

Scheme 5-1 Metal catalyzed cross-coupling reaction of alkynylmetals i oxidative addition, ii transmetallation, iii reductive elimination. Scheme 5-1 Metal catalyzed cross-coupling reaction of alkynylmetals i oxidative addition, ii transmetallation, iii reductive elimination.
Cross-coupling reactions of alkynylmetal reagents with sp carbon atoms.. 203... [Pg.277]

Cross-coupling Reactions of Alkynylmetal Reagents with sp Carbon Atoms... [Pg.383]

Negishi et al. [258] have initially suggested that the applicable metals for the alkynyl cross-couplings may be limited to Zn, Sn, B, and to a lesser extent Al. Nevertheless, the recent significant progress in ligands, catalysts, and reaction conditions has paved the way for efficient cross-coupling of several other alkynylmetals. [Pg.739]


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Alkynylmetals

Alkynylmetals metal catalyzed cross-coupling reaction

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