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Critical composition molecular elevation

When the third bst ce dissnlms m only one of the two liquids the mutual solubility of the latter is diminished, and the temperature at which the system becomes homogeneous is raised, in the case of liquids having an upper critical solution temperature, and lowered in the case of liquids having a lower critical solution temperature. The elevation (or the lowering) of temperature depends not only on the nature and amount of the added substance, but also on the composition of the liquid mixture. When the two liquids are present in the proportions of the critical composition, it is found that, for concentrations of the addendum (non-electrolyte) less than about 0 i molar, the elevation (or depression) of the critical solution temperature is nearly proportional to the amount added. The elevation (or depression) of the critical solution temperature for small equi-molecular quantities of different substances is, however, not constant, but depends on the nature of the substance added. In the following tables are given the values for the elevation of the critical solution temperature of phenol and water by naphthalene (soluble only in phenol) and by potassium chloride (soluble only in water). E represents the molecular elevation of the critical solution temperature —... [Pg.97]


See other pages where Critical composition molecular elevation is mentioned: [Pg.261]    [Pg.100]    [Pg.339]    [Pg.307]    [Pg.477]    [Pg.137]    [Pg.296]    [Pg.139]    [Pg.440]    [Pg.139]    [Pg.412]    [Pg.216]   
See also in sourсe #XX -- [ Pg.97 ]




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