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Cp2M + complexes, structures bonding

A 16-electron, d° Cp2M(R)X species contains one low-lying metal-centered LUMO localized in the equatorial plane between the Cp ligands which is utilized for substrate coordination (Fig. 1) (11). Zr—X r-bonding (X = OR, halide, etc.) utilizes this orbital and generally results in decreased reactivity (5). The electronic structure of a Cp2Zr(R)(L) complex is similar to that of neutral analogs, but the LUMO is stabilized by the metal... [Pg.326]

Ho J, Breen TL, Ozarowski A, Stephan DW (1994) Early metal mediated P-P bond formation in Cp2M(PR)2 and Cp2M(PR)s complexes. Inorg Chem 33 865-870 Shevelkov AV, Dikarev EV, Popovkin BA (1994) Helical chains in the structures of Hg2PsBr and Hg2P3Cl. Z Krist 209 583-585... [Pg.223]

See other pages where Cp2M + complexes, structures bonding is mentioned: [Pg.196]    [Pg.211]    [Pg.181]    [Pg.195]    [Pg.206]    [Pg.2049]    [Pg.3]    [Pg.200]    [Pg.231]    [Pg.141]    [Pg.327]    [Pg.347]    [Pg.349]    [Pg.63]    [Pg.397]    [Pg.398]    [Pg.15]    [Pg.228]    [Pg.194]    [Pg.349]    [Pg.406]    [Pg.206]    [Pg.435]    [Pg.2049]    [Pg.335]    [Pg.145]   
See also in sourсe #XX -- [ Pg.345 ]



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Cp2M

Cp2M + complexes, structures

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