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Countercurrent melt crystallization in a column

We have studied crystallization from a solution in a CSTS in Section 6.4.1.1. Crystallization from a melt was studied in Section 6.3.2.3 under conditions where there was bulk [Pg.751]

Generally, mass fraction based concentration units are used in melt crystallization. The corresponding equation is as follows  [Pg.753]

For an end-feed column with the feed having a crystal flow rate of impurity mass fraction a low-melting product flow rate of Wau impurity mass fraction of Uul, an adhering liquid flow rate of u/,d and an impurity mass fraction of Uid, the value of NTUot has been calculated as (Wankat, 1990, p. 182) [Pg.753]

Further, Uia, is usually specified in terms of the purity of the crystal product. An additional impurity balance at the melter end of the column yields the melted product composition Uico via [Pg.753]

Knowing um, Uj and the two flow rates, um, can be determined. The unknowns in this analysis from a parametric point of view are the fraction of adhering melt, u/ici/ tcL, and the value of HTUot- Albertins et al. (1967) obtained a value of HTUot = 12.3 cm for a particular eutectic system (purifying azobenzene). [Pg.754]


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