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Corey-Peterson olefination

The Corey-Peterson olefination is a version of the Peterson olefination that produces trisubstituted (O-rncthyl alkenes with high diastcreoselcctivity via a two-step process. [Pg.172]

P-Elimination of a hetero-substituted C-C single bond. The best-known reactions of this type are the heteroatom -heteroatom (Het -Het ) elimination (Het = O, Hal, S,...), heteroatom -hydrogen (Het -H ) elimination, Peterson olefination, Tschugajew reaction and Corey-Winter olefination. [Pg.176]

Scheme 9.79. A representation of the steps in the pathway for the introduction of a methylene in place of an oxygen in furan-2-carboxaldehyde (furfural) to generate 2-vinylfuran through use of the Peterson olelination process. The Peterson olefination was first reported by Peterson, D. J. J. Org. Chem., 1968,33,780, and has been modified by Corey, E. J. Enders, D. Bock, M. G. Tetrahedron Lett., 1976,7. Scheme 9.79. A representation of the steps in the pathway for the introduction of a methylene in place of an oxygen in furan-2-carboxaldehyde (furfural) to generate 2-vinylfuran through use of the Peterson olelination process. The Peterson olefination was first reported by Peterson, D. J. J. Org. Chem., 1968,33,780, and has been modified by Corey, E. J. Enders, D. Bock, M. G. Tetrahedron Lett., 1976,7.
See other pages where Corey-Peterson olefination is mentioned: [Pg.172]    [Pg.151]    [Pg.172]    [Pg.151]    [Pg.256]    [Pg.45]    [Pg.867]    [Pg.643]    [Pg.37]    [Pg.386]    [Pg.521]    [Pg.124]    [Pg.563]   
See also in sourсe #XX -- [ Pg.151 ]

See also in sourсe #XX -- [ Pg.151 ]



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Corey

Olefinations Peterson

Peterson

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