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Copolymers, moment free energy, chemical

We now illustrate how the moment method is applied and demonstrate its usefulness for several examples. The first two (Flory-Huggins theory for length-polydisperse homopolymers and dense chemically polydisperse copolymers, respectively) contain only a single moment density in the excess free energy and are therefore particularly simple to analyze and visualize. In the third example (chemically polydisperse copolymers in a polymeric solvent), the excess free energy depends on two moment densities, and this will give us the opportunity to discuss the appearance of more complex phenomena such as tricritical points. [Pg.304]


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