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Cope rearrangement metal catalysis

An experimental aspect of the Cope rearrangement particularly important in synthesis is the feature that it is frequently subject to catalysis. We have already seen that in the anionic oxy-Cope rearrangement enormous rate enhancements are realized by the incorporation of an alkoxide ion in the substrate. In many Cope rearrangements similar rate enhancements are achieved by the addition of catalysts, particularly acids and metals. ... [Pg.798]

Several mechanisms have been proposed for palladium catalysis of Cope rearrangements. Overman, who has examined metal ion catalysis of a number of 3,3-sigmatropic rearrangements, considers this an... [Pg.802]

A comprehensive review of the catalysis of the Cope and Claisen rearrangements includes catalysis by transition metal complexes. ... [Pg.392]

See other pages where Cope rearrangement metal catalysis is mentioned: [Pg.580]    [Pg.576]    [Pg.799]    [Pg.800]    [Pg.802]    [Pg.822]    [Pg.1660]    [Pg.2548]    [Pg.799]    [Pg.800]    [Pg.822]    [Pg.303]    [Pg.239]    [Pg.364]    [Pg.257]    [Pg.117]   
See also in sourсe #XX -- [ Pg.799 ]

See also in sourсe #XX -- [ Pg.799 ]



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Cope rearrangement catalysis

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