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Coordination geometry vibrational spectra

By using a variety of techniques, the species MX, MX2, MX3, and MX4 have been observed in titrations of Hg(II) with varying quantities of Cr. Importantly, increasing the coordination number results in a lower frequency vibration in the Raman spectrum (22). For Zn and Cd, MXj" is not trigonal planar in tri-n-butyl phosphate solutions, as evidenced by observation of an IR band for the totally symmetric stretching mode forbidden in symmetry for Hg(II), the D,/, geometry is observed. [Pg.369]

See other pages where Coordination geometry vibrational spectra is mentioned: [Pg.95]    [Pg.321]    [Pg.42]    [Pg.308]    [Pg.110]    [Pg.89]    [Pg.5204]    [Pg.245]    [Pg.24]    [Pg.136]    [Pg.5203]    [Pg.370]    [Pg.439]    [Pg.241]    [Pg.109]    [Pg.874]    [Pg.101]    [Pg.50]    [Pg.82]    [Pg.112]    [Pg.23]    [Pg.1347]    [Pg.1386]    [Pg.21]    [Pg.82]    [Pg.376]    [Pg.29]    [Pg.588]    [Pg.312]    [Pg.266]    [Pg.15]    [Pg.46]    [Pg.118]    [Pg.132]    [Pg.134]    [Pg.24]    [Pg.6255]    [Pg.146]    [Pg.532]    [Pg.24]    [Pg.367]    [Pg.212]    [Pg.260]    [Pg.874]    [Pg.1138]    [Pg.6254]    [Pg.98]    [Pg.512]    [Pg.3186]    [Pg.3225]   
See also in sourсe #XX -- [ Pg.237 , Pg.238 ]

See also in sourсe #XX -- [ Pg.237 , Pg.238 ]



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Coordination geometries

Vibrational coordinate

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