Conventional hydrogen bonding

CONVENTIONAL HYDROGEN BONDS THEORETICAL AND EXPERIMENTAL CRITERIA OF HYDROGEN BOND FORMATION... [Pg.6]

An interaction can be taken as a conventional hydrogen bond if its formation corresponds to the following criteria [3] ... [Pg.7]

A modem description of a conventional hydrogen bond as well as its older, more accurate definition are based on Bader s theory of atoms in molecules (AIM theory) [4]. Bader considers matter a distribution of charge in real space of point-like nuclei embedded in the diffuse density of electron charge, p(r). All the properties of matter are manifested in the charge distribution and the topology... [Pg.7]

Electron density pc calculated at the bond critical point and related to the bond order and bond strength is shown in Table 3.4. As shown, the pc values obtained are within the range 0.002 to 0.0035 au, magnitudes typical of conventional hydrogen bonds. [Pg.41]

At the beginning of the 20th century, Huggins [1], Latimer and Rodebush [2], and Pauling [3] introduced the concept of a classical or conventional hydrogen bond A-H- -B as that formed between a (conventional) hydrogen... [Pg.433]

R is usually assumed that a conventional hydrogen bond A-H- -B is formed if the following structural and spectroscopic criteria are obeyed [5-20] ... [Pg.434]

Therefore, it may be concluded that non-conventional hydrogen bonds can play an important role in determining the supramolecular structure of gold complexes. [Pg.337]

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