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Contrast value, high, requirements materials

The copolymer composition produced by these two catalysts can be estimated using the Mayo-Lewis equation [38] and these values of i and r2. Figure 10 depicts the hypothetical comonomer content in the polymer (F2) as a function of the mole fraction of comonomer in the reactor (f2). The good incorporator produces a material with higher F2 as f2 increases. In contrast, the composition from the poor incorporator is relatively flat across a broad range and increases only at very high values of/2. The F2 required to render the copolymer amorphous is comonomer-dependent for 1-octene, this value is near 0.19. In this hypothetical system, the good incorporator produces that composition at f2 = 0.57, at which the poor incorporator incorporates very little comonomer (F2 = 0.01). [Pg.82]


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See also in sourсe #XX -- [ Pg.96 ]




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Contrast value, high, requirements

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