Consistency between Electrochemical and Structural Data

Size-dependent peak shift is clear both for samples in equilibrium at 3.30 V and at 3.50 V as shown in Fig. 1.8. The lattice 

Further inspections on the solid solution compositional domain were performed for the electrochemically adjusted LixFeP04 with a particle size of 40 nm, which allow largest miscibility in the present 

All the data are on the line of Vegard s law of FeP04-LiFeP04 solid solution without any systematic deviation and further support the two main conclusions of this paper with no ambiguity (i) validity of the size-dependent miscibility gap model in Lij FeP04 and (ii) bulk miscibility dominates the electrochemical behavior of LixFeP04 at least for particle sizes larger than 40 nm. 

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