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Conjugated unsaturated systems allylic substitution

The presence of /3-unsaturation normally leads to the formation of the corresponding conjugated system. The usual order of reactivity of a /3 proton is thus benzylic, allylic > CH3 > CH2 > CH. However, this preference can be offset by additional substitution at the more activated position competition between the /3-elimination modes leads to a mixture of regio-isomers as shown in Scheme 20. [Pg.1176]


See other pages where Conjugated unsaturated systems allylic substitution is mentioned: [Pg.288]    [Pg.277]    [Pg.114]    [Pg.27]    [Pg.243]    [Pg.300]    [Pg.693]    [Pg.268]    [Pg.375]    [Pg.118]    [Pg.186]    [Pg.296]    [Pg.129]    [Pg.46]   
See also in sourсe #XX -- [ Pg.582 ]

See also in sourсe #XX -- [ Pg.586 , Pg.587 , Pg.588 , Pg.589 ]




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Allyl system

Allyl systems conjugation

Allylic substitution

Conjugate allylation

Conjugate substitution

Conjugate system

Conjugated system conjugation)

Conjugated systems

Conjugated unsaturated system

Conjugated unsaturation

Substituted systems

Substitution systems

Unsaturated systems

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