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Conjugated compounds, 1,2-addition with organolithium reagents

The chemical behavior of heteroatom-substituted vinylcarbene complexes is similar to that of a,(3-unsaturated carbonyl compounds (Figure 2.17) [206]. It is possible to perform Michael additions [217,230], 1,4-addition of cuprates [151], additions of nucleophilic radicals [231], 1,3-dipolar cycloadditions [232,233], inter-[234-241] or intramolecular [220,242] Diels-Alder reactions, as well as Simmons-Smith- [243], sulfur ylide- [244] or diazomethane-mediated [151] cyclopropanati-ons of the vinylcarbene C-C double bond. The treatment of arylcarbene complexes with organolithium reagents ean lead via conjugate addition to substituted 1,4-cyclohexadien-6-ylidene complexes [245]. [Pg.36]

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See also in sourсe #XX -- [ Pg.615 ]



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Addition conjugated with

Compounding with additives

Conjugate addition compounds

Conjugate addition organolithium reagents

Conjugate addition reagents

Conjugate: compounds

Conjugated compounds

Conjugated compounds with

Conjugation, reagents

Organolithium compounds

Organolithium compounds conjugate additions

Organolithium compounds, 1,4-addition

Organolithium conjugate addition

Organolithium reagents

Organolithium reagents compounds

Organolithiums addition

Organolithiums reagents

Reagent addition

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