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Conformational gearing motion

Iroff and Mislow (25) earned out empirical force-field calculations on this molecule and confirmed that the expected nonbonded interaction forces the molecule to undergo a coordinated twist motion ( gear effect ). Their calculations also indicated that the molecule exists, not only in this ground state conformation with T symmetry, but also in a higher energy conformer with achiral S4 symmetry. The energy gap, A T, between the T and S4 forms was found to... [Pg.242]

See other pages where Conformational gearing motion is mentioned: [Pg.136]    [Pg.25]    [Pg.83]    [Pg.153]    [Pg.339]    [Pg.397]    [Pg.402]    [Pg.41]    [Pg.41]    [Pg.352]    [Pg.345]    [Pg.163]    [Pg.25]    [Pg.62]    [Pg.399]    [Pg.169]    [Pg.1125]    [Pg.441]    [Pg.442]    [Pg.450]    [Pg.351]    [Pg.269]    [Pg.584]   
See also in sourсe #XX -- [ Pg.396 ]



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