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Conformation angle kinetics

Assuming that the deposition process is dominated by equilibration rather than kinetic trapping effects, Rivetti et al. have performed statistical analysis of the chain conformation in terms of the mean-square end-to-end distance, , and the mean-square bend angle, <02> [493]. Both values are well described theoretically for both two-dimensional and three-dimensional states [494-498]. For a two dimensional system, the following formula can be used ... [Pg.143]

Conformational effects not only determine TICT formation kinetics but can also play a role in determining the TICT state properties. It has to be borne in mind that properties such as the radiative rate constant kf (or oscillator strength f) and the dipole moment n can strongly depend on the twist angle especially in the neighborhood of 90°, because kf minimizes and n maximizes for the... [Pg.280]

See other pages where Conformation angle kinetics is mentioned: [Pg.6]    [Pg.124]    [Pg.512]    [Pg.596]    [Pg.108]    [Pg.408]    [Pg.411]    [Pg.376]    [Pg.108]    [Pg.49]    [Pg.87]    [Pg.321]    [Pg.183]    [Pg.255]    [Pg.792]    [Pg.103]    [Pg.47]    [Pg.51]    [Pg.148]    [Pg.339]    [Pg.88]    [Pg.58]    [Pg.235]    [Pg.983]    [Pg.1307]    [Pg.115]    [Pg.411]    [Pg.401]    [Pg.166]    [Pg.43]    [Pg.620]    [Pg.38]    [Pg.141]    [Pg.81]    [Pg.184]    [Pg.235]    [Pg.198]    [Pg.209]    [Pg.26]    [Pg.83]    [Pg.105]    [Pg.417]    [Pg.49]    [Pg.118]    [Pg.13]    [Pg.225]    [Pg.104]   
See also in sourсe #XX -- [ Pg.142 ]



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Angles conformation

Conformation kinetics

Conformational angles

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