Configurational integral thermodynamic properties from

Mayer discovered an ingenious way out of this conundrum. Recall from Chapter 15 that the thermodynamic properties of a system of N molecules at volume V and temperature T can be evaluated from the configuration integral Z ... 

The thermodynamic properties for a system of N molecules (or N atoms) can be rigorously accounted for using statistical mechanics. Monte Carlo simulation methods provide the foundation for numerically simulating the configurational integral shown in Eq. (B13) that arise from the statistical mechanics treatment. 

It is apparent from Eq. 17.3.7 that, if the configuration integral can be evaluated, all thermodynamic properties of the fluid can be determined (See Example 17.1)- provided, of course, that t available (Section... 

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