Conditions of CPS Stability During Storage

Estimation of possible limits of variation of the parameters of the Eqs. (5.51) using data on the properties of the Li/SOCl2 system cells summarised in [27] gave the 

11 Graphical lepiescmtatirai of the critical situation under uncontrolled self-acceleration of an exothermal reactirai [28] 

Combinations of parameters are possible, however, at which, during storage, curve W2 will gradually shift upwards. The stationary states 1 and 2 will converge and, at some critical value of dimensionless variable, will disappear. This bifurcation will lead to the development of local heat source and to catastrophic destruction of the cell. The condition of this is 

The appearance of instability has been analysed for two limiting cases of Eq. (5.51)  

The internal resistance of the cell decreases with increasing temperature in accordance with the same regularity as an increase in the rate of chemical interaction, i.e. e = e,.. 

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