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Complex SISHA interactions

Stabilizing SISHA interactions were invoked to account for the unusual properties of the chelate complexes [Ru(H)2 (ri -HSiR2)2X (PCy3)2] (141). These compounds were prepared by disilane additions to [Ru(H)2(ri -H2)2(PCy3)2]... [Pg.298]

Such secondary interactions between silicon and hydrogen atoms (SISHAs) are hydrogen-bonding like and have been observed crystallographically in several other silane and H2 complexes with r -hydrides (see below). [Pg.675]

See other pages where Complex SISHA interactions is mentioned: [Pg.299]    [Pg.300]    [Pg.299]    [Pg.300]    [Pg.296]    [Pg.298]    [Pg.302]    [Pg.296]    [Pg.298]    [Pg.302]   
See also in sourсe #XX -- [ Pg.632 ]



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