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Complex branched-chain mechanism branching rate

This opened the possibility of ascertaining quantitative characteristics in the numerous individual reactions comprising the complex mechanism of oxidative chain reactions. Thus, rate constants have been determined for reactions with respect to their initiation and the branching, extension, and chain rupture, establishing specific details concerning the influence of solvents, reaction vessel surfaces, and other factors on the mechanism of individual reactions. Results of these investigations have... [Pg.14]

At 125°C, the results were more complex. In some cases both d>(c-C3Fe) and d>(C2F40) exceeded unity a branched chain mechanism was indicated. However, by suitable manipulation of the data, some rate-constant ratios could also be estimated at this temperature and they are also listed in Tables XIX and XX. [Pg.111]

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See also in sourсe #XX -- [ Pg.77 , Pg.78 ]



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Branched chain

Branching mechanisms

Branching rate

Chain branching

Chain complexes

Complex branched-chain mechanism

Complexation rates

Complexity chains

Mechanism complexes

Rate mechanism

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