Complex as an Equivalent to PSiP-Palladium Hydride Complexes

Synthesis and Reaction ofii - Si-H)Pd 0) Complex as an Equivalent to PSiP-Palladium Hydride Complexes 

The coupling constant is observed to be 110 Hz by non H-decoupled Si NMR in tetrahydrofuran (THE) at room temperature, which is much larger than typical values found for H-M-Si complexes ( 20Hz) but significantiy smaller than that of silane 44 itself = 204 Hz), supporting weakening of the Si- H bond 

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