Comparison of experimentally measured

Fig. 23. Comparison of experimentally measured mole fraction profiles for CH3CI, CH, and Oj with those determined using the DCKM presented in Table XIV.

The extent of this failure is evident from comparisons of experimental measurements of rate and equilibrium constants. One comparison in the literature is provided by Ritchie and coworkers study of the relatively stable cation, pyronin (the 3,6-bis(dimethylamino)xanthylium cation 71) with a series of nucleophiles.252 Another example is McClelland s measurements of rate and equilibrium constants for the reactions of halide and acetate ions with the trityl cation.19 As already mentioned fluoride and acetate are less reactive than bromide and chloride despite their equilibrium affinities being much greater. This is reflected indeed in the much lower rates of solvolysis of the fluoride and acetate than bromide or chloride as leaving groups... 

Figure 5. Quantitative comparison of experimentally measured values of for C02 in various polymers with the predictions of Equation 3. poly(ethylene terephthalate) at 25, 35, 5,...

Table 15-7 Comparison of experimentally measured and calculated migration values, mF(/A (pg dm 2) for Irgafos from HDPE into 95 % ethanol at 40 °C.

Figure 11. Comparison of experimentally measured residual weight to that predicted from the reaction model at 312 °C. Key to predicted residual weights —, predicted —, W. and , The experimental...

Figure 7. Comparison of experimental measurement of amorphous fraction accumulation as a function of dose with curves fit to various models for irradiation induced amorphization (modified after Weber 2000).

Figure 19. Comparison of experimentally measured amounts of styrene in copolymer produced in a controlled (O) and uncontrolled (+) semi-batch reactor...

Figure 5. Comparison of experimentally measured and theoretically predicted water absorption vs. equivalent weight for standard Nafion...

Figure 9. Comparison of experimentally measured protein content frequency function (dots) for S. pombe, grown in a chemostat with D = 0.246 hr , with best fit simulations (lines) using the kinetic forms of Equation 2. Reproduced, with permission, from Ref. 25. Copyright 1981, John Wiley Sons, Inc.

Figure 5.3 Comparison of experimental measurements and various model predictions for H2 at the fuel channel exhaust. Nominal inlet mole fractions at the fuel channel are 20% CH4, 2.8% H2, and 77.2% Ar. Inlet mole fractions at the electrolyte channel are 50% CO2, 1.75% H2 and 48.25% Ar.

Boltzmann equation results for transport coefficients have, until recently, come from a comparison of experimental measurements of 17 with theoretical values, over a large temperature range. 

Comparison of Experimentally Measured and Analytically Predicted Material Reactivity Worths in the Flexible Critical E3 periment (FCX), V. S. Oblock. S. Salah, W. e Freidhof (W-Astro)... 

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