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Combining Ratios and Spin States

A more generally useful measure for the purpose of this book is the (free) energy difference between reactions at electrodes in water at 298 K such as [Pg.48]

Usual Spin States for Some Metal Ions [Pg.49]

Fe Low-spin, high-spin (d6) High-spin, low-spin (d5) [Pg.49]

Spin-State Switches for Some Metal Complexes [Pg.50]

Note phen is 1, 10 orthophenanthroline. Note the change to low-spin, paired d electron, states gains tr-acceptor and /r-donoi strength offsetting spin-pairing energy. [Pg.50]


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