Cobalt perchlorate alkane oxidation

Lead(IV)277 and silver(III)301 trifluoroacetates in TFA also oxidize alkanes at room temperature to give alkyl trifluoroacetates [see also Section III.D.3 for reactions of alkanes with Pd(II) trifluoroacetate]. The stoichiometric oxidation of cyclohexane to a mixture of cyclohexanol, cyclohexanone, and adipic acid by cobalt(III) perchlorate in aqueous acetonitrile has also been reported.240... 

Cobalt(in) perchlorate in aqueous MeCN oxidizes alkanes at room temperature with an apparent secondary > primary > tertiary selectivi pattnm. This pattnm may not be real, however, because die product of tertiary attack may be much more sensitive to further oxidation. 2-Methylpentane was... 

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See also in sourсe #XX -- [ ]

See also in sourсe #XX -- [ ]

See also in sourсe #XX -- [ , ]

See also in sourсe #XX -- [ , ]

See also in sourсe #XX -- [ ]

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