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Cobalt dioxygen adducts

DR. ENDICOTT In fact, the cobalt-eyelam-oxygen adduct can have a very short lifetime depending on the competition reactions. If the cobalt dioxygen adduct is generated in the presence of greater concentrations of CoAA([l4]aneN ), the intermediate lifetime is clearly shortened. The classical studies made by Ralph Wilkins, for instance, were carried out under conditions in which intermediates only achieved small stationary state concentrations. [Pg.437]

A different approach is then necessary and this has been made by Tovrog et al. (48) in a discussion of a series of cobalt dioxygen adducts, where, 70... [Pg.14]

An unusual cobalt-dioxygen adduct is formed in the reaction of O2 with [Co -(CN)a(PMe2Ph)3], in that during the course of reaction a dimeric complex is formed with the exclusion of only a single mole of dimethylphenylphosphine. The rate law of the form... [Pg.109]

See other pages where Cobalt dioxygen adducts is mentioned: [Pg.11]    [Pg.22]    [Pg.183]    [Pg.78]    [Pg.776]    [Pg.776]    [Pg.776]    [Pg.779]    [Pg.779]    [Pg.781]    [Pg.776]    [Pg.776]    [Pg.776]    [Pg.779]    [Pg.779]    [Pg.4230]    [Pg.4230]    [Pg.4230]    [Pg.4233]    [Pg.4233]    [Pg.4235]    [Pg.222]   
See also in sourсe #XX -- [ Pg.14 , Pg.15 , Pg.28 , Pg.29 , Pg.30 , Pg.33 , Pg.78 , Pg.79 , Pg.80 , Pg.81 ]



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