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Cluster complexes dimers, octahedral clusters

The structure of [Mo3S4(dmit)3] (dmit=l,3-dithiole-2-thione-4,5-dithiolate) represents one of the rare examples of M3S4 clusters where each metal atom appears as pentacoordinate instead of its more common type-I structure octahedral environment [39]. Complexes [M3Q4(dmit)3] (M = Mo, W Q = S, Se) degrade in air with an almost quantitative yield and afford a series of M(V) dimers of formula [M202(//-Q)2(dmit)2] where the oxygen atoms are in a syn configuration. [Pg.114]

See other pages where Cluster complexes dimers, octahedral clusters is mentioned: [Pg.47]    [Pg.48]    [Pg.64]    [Pg.193]    [Pg.44]    [Pg.47]    [Pg.48]    [Pg.64]    [Pg.435]    [Pg.344]    [Pg.55]    [Pg.317]    [Pg.990]    [Pg.94]    [Pg.35]    [Pg.384]    [Pg.92]    [Pg.588]    [Pg.289]    [Pg.50]    [Pg.154]    [Pg.538]    [Pg.3430]    [Pg.5189]    [Pg.5861]    [Pg.139]    [Pg.162]    [Pg.5]    [Pg.66]    [Pg.537]    [Pg.3429]    [Pg.5188]    [Pg.5860]    [Pg.2427]    [Pg.129]    [Pg.284]    [Pg.101]    [Pg.323]    [Pg.53]    [Pg.146]    [Pg.304]   
See also in sourсe #XX -- [ Pg.63 , Pg.64 , Pg.65 ]

See also in sourсe #XX -- [ Pg.63 , Pg.64 , Pg.65 ]



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Cluster complexes

Cluster complexes octahedral

Dimeric clusters

Dimeric complexes

Octahedral clusters

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