Clausius-Mossotti relationship

Many authors have discussed a dielectric catastrophe and the Mott transition in terms of the Clausius-Mossotti relationship... [Pg.159]

If (RIV) = 1, the resultant force on the localized electron vanishes, the electron is set free, and the system acquires metallic status. The previous statements may be recast in slightly different form using the venerable Clausius-Mossotti relationship (81), where... [Pg.170]

Using Equations (11.3)-(11.5) it is possible to derive the most widely used relationship between relative permittivity and polarisability, the Clausius-Mossotti relation. Equation (11.6), usually written ... [Pg.341]

This relationship as such is not well obeyed for most compounds if the static or low-frequency relative permittivity is used, as can be judged from Table 11.1. The relationship can be correctly interpreted by using the relative permittivity due to electronic polarisation in the equation. With this in mind, substitution of the relationship given in Equation (11.10) into the Clausius-Mossotti equation yields the Lorentz-Lorenz equation ... [Pg.342]

The Clausius-Mossotti equation identifies the relationship between the dielectric constant (k), the molecular polarizability (a), aud the molar volume (V ,) of a material as follows (Shepard 1949) ... [Pg.211]

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