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Cinnamic acids, hydrodimerization

Baizer and coworkers established the most brilliant industrial electroorganic synthesis of the hydrodimerization of acrylonitrile to adiponitrile. They extended this hydrodimerization to a variety of activated olefins and in some cases [41 3] paid attention to the stereochemistry of products. However, their stereochemical data were not enough to discuss the stereochemical course of the reaction. Afterward, an attempt was made to provide a working hypothesis in the hydrodimerization of cinnamates by considering an orientated adsorption of radical anion intermediates on a cathode surface, but this was not persuasive because of a lack of experimental data on the stereochemistry of both the starting olefins and products. Recently Utley and coworkers [44-46] have reported stereochemical data of hydrodimers derived from a variety of cinnamic acid esters with chiral alcohol components. [Pg.1055]


See other pages where Cinnamic acids, hydrodimerization is mentioned: [Pg.429]    [Pg.69]    [Pg.811]    [Pg.67]    [Pg.142]   
See also in sourсe #XX -- [ Pg.811 ]




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Cinnamate

Cinnamates

Cinnamic 4-

Cinnamic acid

Cinnamic acid/cinnamate

Cinnamics

Hydrodimerization

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