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Chromium complexes excited-state lifetimes

Manipulation of Doublet Excited State Lifetimes in Chromium (III) Complexes... [Pg.85]

Thus the activation volume AV for the rate constant kp of an individual ES reaction pathway can be evaluated if the pressure dependencies of the photoreaction quantum yield, of intersystem crossing and of the ES lifetime can be separately determined. However, such parameterization becomes considerably more complex if several different excited states are involved or if a fraction of the photosubstitution products are formed from states that are not vibrationally relaxed with respect to the medium. Currently, parameterization of pressure effects on photosubstitutions has been attempted for a limited number of metal complexes. These include certain rhodium(III) and chromium(III) amine complexes and some Group VI metal carbonyls, which will be summarized here. [Pg.95]

See other pages where Chromium complexes excited-state lifetimes is mentioned: [Pg.139]    [Pg.47]    [Pg.209]    [Pg.150]    [Pg.151]    [Pg.88]    [Pg.168]    [Pg.32]    [Pg.32]    [Pg.40]    [Pg.201]    [Pg.136]    [Pg.145]   
See also in sourсe #XX -- [ Pg.85 , Pg.86 , Pg.87 , Pg.88 , Pg.89 , Pg.90 , Pg.91 , Pg.92 , Pg.93 , Pg.94 , Pg.95 , Pg.96 , Pg.97 , Pg.98 ]



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