Chlorotricarbonyl rhenium

A series of chlorotricarbonyl rhenium(I) complexes based on benzathiazole derivatives have been reported [34]. One of the chlorotricarbonyl rhenium(l) complexes, shown in Fig. 38.3c, exhibits a solar energy efficiency of around 1.43-1.76% [44]. Compared to other rhenium(l) 2,2 -bipyridine complexes, these were found to have a redshifted absorption because the heterocyclic ligands have lower jr-to- 7r energy levels [44]. 

Chan WK, Hui CS, Man KYK, et al. Synthesis and photosensitizing properties of conjugated polymers that contain chlorotricarbonyl bis(phenylimino)acenaphthene rhenium(I) complexes. Coord Chem Rev 2005 249 1351-9. 

Bis p-chlorotricarbonyl-(l -phenyl-1 -hydroxobut-1 -en-3-one)rhenium(i), [Re(CO)3Cl PhC(OH)=CHCOMe ]2, is one of a series of compounds which have been obtained by treating Re(CO)5Cl with P-diketones and it has been... 

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See also in sourсe #XX -- [ ]

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