Chloromethyl peroxy

C(6>-acetylation, 184 bromination, 184 chlorinatiou, 184 chloromethylation, 184 dehydrogenation, xSg deuteration, 183 huorination, 184 formylation (Vdsmeier), 184 methylation, 184 oxidation (peroxy-acid), 184 oxidation (photochemical), 447 photolysis, 431... 

Phosphorus(y) Compounds. The chemistry of phosphate species containing a peroxy linkage and the stereochemical implications of reaction mechanisms at phosphorus(v) have been reviewed. The cyclic 1,3,2-dioxaphospholans derived from meso- and ( )-hydrobenzoin show different n.m.r. spectra, and the crystal structures of the 2-phenoxy- and 2-/>-bromophenoxy-5-chloromethyl-5-methyI-2-oxo-l,3,2-dioxaphosphorinans have been determined. Factors influencing the stereochemistry in substituted 1,3,2-dioxa-phosphorinans as shown mainly by n.m.r. data are considered in a number of papers. Changes in the O—H stretching frequency of phenol in the... 

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