Chloro chlorodimethylsilane

A reaction vessel equipped with a Dean-Stark decanter was charged with 10 parts of the condensation polymer of 2,2-bis(hydroxymethyl)propionic acid having a Mn of 2920 daltons, a Mw of4280 daltons, and a PDI of 1.47. This mixture was then treated with tin(di(chloro-dimethylsiloxy)-tin chlorodimethylsilane) (0.25 parts), ethyl acrylate (100 parts), and hydroquinone (0.05 parts). The mixture was then heated to between 92°C and 95°C so that the amount of distillate to the decanter was 15 to 20 parts per hour. Fresh ethyl acrylate was added to the reaction vessel as needed while the reaction continued for 20 hours. 

Chloro-N-(2,6-dimethylphenyl)-N-(1H-pyrazol-1-ylmethyl) acetamide. See Metazachlor Chlorodimethylphenylsilane. See Phenyidimethylchlorosilane Chlorodimethylsilane. See Dimethylchlorosilane Chlorodimethylvinylsilane. See Vinyidimethylchlorosilane... 

A solution of indene and Speier s catalyst was treated with trichlorosilane, chlorodimethylsilane or dichloromethylsilane, the reaction mixture was stirred at 160°C for several hours. After removal of excess hydrosilanes, trichloro(l-indanyl)silane (la), dichloro(l-indanyl)methylsilane (lb), and chloro(l-indanyl)dimethylsilane (Ic) were isolated by distillation as colorless liquids in yields of... 

Generation of ChIoro(lithiomethyl)dimethylsilane. Treatment of (bromomethyl)chlorodimethylsilane in THF/ether with 1 equiv of n-butyllithium in hexanes at — 120°C produces chloro (lithiomethyl)dimethylsilane. This lithiated derivative spontaneously eliminates LiCl to give an intermediate silaethylene species, which undergoes dimerization to afford 1,1,3,3-tetramethyl-1,3-disilacyclobutane (45%), together with a small amount of l,l,3,3,5,5-hexamethyl-l,3,5-trisilacyclohexane (15%) (eq9). ... 

Chlorodimethylphenylsilane, C-00103 Chlorodimethyl-2-propenylsilane, C-00104 Chlorodimethylsilane, C-00105 Chloro(iodomethyl)dimethylsilane,... 

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