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Chlorination of alkynes

Chlorination of alkynes. The reaction of iodobenzene dichloride with alkynes (CHCI3, reflux, azobisisobutyronitrile initiation) results in anri-addition to give E-dichloroalkenes (equation I). Use of chlorine (ionic or radical) leads to complex mixtures. ... [Pg.300]

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Alkynic chlorine

Chlorination alkynes

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