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Chiral ruthenabicyclic complex

Chiral ruthenabicyclic complexes, where a BINAP and a diamine provide chelation to produce the rings, provide excellent catalysis of hydrogenation of ketones, giving >99% ee and turnover frequency of 35000min for acetophenone. Spectroscopic and deuteration experiments suggest that the ruthenabicyclic structure is retained throughout. ... [Pg.47]

Matsumura, K. Aral, N. Hori, K. Saito, T. Sayo, N. Ohkuma, T. Chiral ruthenabicyclic complexes Precatalysts for rapid, enantioselective, and wide-scope hydrogenation of ketones. /. Am. Chem. Soc. 2011, 133, 10696-10699. [Pg.114]

See other pages where Chiral ruthenabicyclic complex is mentioned: [Pg.70]    [Pg.86]    [Pg.70]    [Pg.86]   
See also in sourсe #XX -- [ Pg.70 , Pg.86 ]



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