Charge transfer spectroscopy

Lever ABP, Gorelesky SI (2004) Ruthenium Complexes of Non-Innocent Ligands Aspects of Charge Transfer Spectroscopy 107 77-114 LiB, see He J (2005) 119 89-119... 

The theoretical problems associated with calculating nonlinear polarizabilities is closely linked to the field of charge transfer spectroscopy and reactivity as well as the field of multi-photon and excited state spectroscopy. It is likely that theoretical methods from these fields will contribute to a deeper understanding of nonlinear optical phenomena in organic, inorganic, and organometallic compounds. 

A similar dependence of o-7t conjugation on stereochemistry is evident from the charge-transfer spectroscopy of benzyltrimethylstannane 205 and the bicyclic stannane 206 (where the C-Sn bond is constrained to lie in the nodal plane of the n system)175 whereas the charge-transfer frequency of 206 is identical with the parent hydrocarbon 207, in benzyltrimethylstannane 205, in which C7-7t conjugation is possible, the charge-transfer frequency is lowered by 6800 cm-1 compared with toluene. 

Lever ABP, Dodsworth ES. Electrochemistry, Charge Transfer Spectroscopy and Electronic Structure. In Solomon El, Lever ABP, eds. Inorganic Electronic Structure and Spectroscopy. New York John Wiley Sons, Inc., 1999 227-291. 

Finally, it must be pointed out that a great deal of work was published on related metal assembled compounds such as linear or circular helicates [57], cages [58], and rack-type complexes [59]. Flowever, since little or no discussion related to charge-transfer spectroscopy or photoinduced electron transfer was reported, they will not be presented here. 

Weit, S. K. Ferraudi, G. Grutsch, P. A. Kutal, C. Charge-transfer spectroscopy and photochemistry of alkylamine cobalt(III) complexes. Coord. Chem. Rev. 1993, 128, 225-243. 

Charge Transfer Spectroscopy—Metal-ligand Bonding 695... 

Charge Transfer Spectroscopy— Metal-digand Bonding... 

Aspects of Charge Transfer Spectroscopy A. B. P. Lever S. L. Gorelsky... 

Charge Transfer Spectroscopy of Cyano-Bridged Complexes... 

---