Charge transfer chemistry

More recently we have turned our attention to the influence of dynamic variations in stacking on base-base CT. Here again Ap is particularly useful given its demonstrated charge transfer chemistry in DNA, and its ability to report on the structure and dynamics of the DNA environment. Using spe-... 

The emeraldine salt, (II-7), can also be obtained directly from leucoemeraldine by charge transfer doping, with reactions analogous to (II-1) and (II-3). Thus, the doping of polyaniline has been described as two-dimensional in a space where one axis describes the charge transfer chemistry and the second, orthogonal axis describes the acid/base (protonation) chemistry [37]. 

The complex reaction order dependence of exchange current density in H2 and H2O are quite different from the ones used for global charge transfer chemistry [75]. The parameter p is given by [73]... 

Electron hydration is quite an interesting and important issne and many experimental and theoretical studies have already been devoted to the issue. [93, 123, 154, 166, 167, 199, 209, 341, 374, 382] It is a prototjqie of solution-phase chemistry in polar solvent. Also, the dynamics are expected to provide an important insight into charge-transfer chemistry. 

Motivations for the study of nonlinear optical phenomena in polydiacetylenes (PDAs) are discussed. Recent progress in the fabrication and characterization of PDA waveguides is summarized along with approaches to the interpretation of the observed nonlinear optical phenomena. Attempts to create a carrier population in PDAs via charge transfer chemistry are reviewed. The... 

In view of the lack of recorded success of attempts to modify PDA properties by charge transfer chemistry, the observation (48) that treatment of poly-DCH with SbF in pentane resulted in a dark... 

It can be seen that all these studies share a common theme where the particle charge-transfer chemistry is closely correlated to their molecular structure. In fact, a host of nanoparticle structural parameters have been identified, such as core size, ligand chemical structure, and interparticle separation. These have been the main focus of most earlier work, 2-24 several rather comprehensive... 

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