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Charge displacement technique

Indirect UV detection is a common technique which has been applied to the analysis of cations and anions. A UV-absorbing anion plus an electroos-motic flow modifier is added to the electrolyte. The displacement chromophore permits indirect photometric detection. Optimum separations can be achieved by choosing an electrolyte anion which has a mobility similar to the ions of interest. Some investigators have used conductivity detection, while others have used indirect laser-induced fluorescence for anion detection. Detection of the nonfluorescence analyte is obtained by charge displacement of the fluorophore (339,340). [Pg.349]

The macromolecular density matrix built from such displaced local fragment density matrices does not necessarily fulfill the idempotency condition that is one condition involved in charge conservation. It is possible, however, to ensure idempotency for a macromolecular density matrix subject to small deformations of the nuclear arrangements by a relatively simple algorithm, based on the Lowdin transform-inverse Lowdin transform technique. [Pg.74]

In this chapter, we have reviewed the experimental researches on the coherent optical phonons detected by novel nonoptical techniques, as well as on their optical control using shaped pulses. TRXRD can separate atomic displacements from collective motions of charges, while TR-THz and TRPE spectroscopies can visualize the ultrafast development of strong interaction... [Pg.60]

To improve interwell communication further, a hydraulic fracturing treatment was performed at a depth of 79 to 84 ft in well 5 to ensure the displacement and detonation of the 300-qt charge of NG1. The effectiveness of the three fracturing techniques was determined by measuring airflow rates between selected wells before and after each test. [Pg.107]


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