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Chaetoglobosin biosynthesis

A new toxic cytochalasin, chaetoglobosin K, isolated from Diplodia macro-spora, has the structure (24), according to the X-ray crystal-structure determination.24 Compared with chaetoglobosin A, metabolite K has additional methyl groups at positions 10 and 11 this raises the interesting possibility (among others) that propionic acid may be implicated in its biosynthesis. [Pg.151]

Kig. 15.1, ess oxidized products using P450 inhibitor in the biosynthesis of chaetoglobosin A (58)... [Pg.143]

The rapid progress in polyketide biosynthesis allowed to identify the biosynthetic gene clusters of several Diels-Alder adducts such as equisetin, chaetoglobosin, spinosyn, chlorothricin, and kijanimicin. Possible enzymes that catalyze the corresponding Diels-Alder reaction in the biosynthesis of these polyketides will be discussed. [Pg.307]

See other pages where Chaetoglobosin biosynthesis is mentioned: [Pg.142]    [Pg.142]    [Pg.142]    [Pg.142]    [Pg.242]    [Pg.142]    [Pg.242]    [Pg.243]    [Pg.545]    [Pg.37]   
See also in sourсe #XX -- [ Pg.142 ]

See also in sourсe #XX -- [ Pg.142 ]



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