Cesium fluoride allylsilane reactions with aldehydes

In fluoride ion catalyzed reactions of allylsilanes, aldehydes are the only carbon electrophiles that work well protodesilylation is unavoidable with most other electrophiles, even in the most rigorously dried media. The most commonly used fluoride ion source, which only needs to be present in catalytic amounts, is TBAF in THF at room temperature or under reflux, benzyltrimethylammonium fluoride may be better, and cesium fluoride in DMF, potassium fluoride with 18-crown-6 in THF, and TASF in polar... 

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See also in sourсe #XX -- [ , ]

See also in sourсe #XX -- [ ]

See also in sourсe #XX -- [ ]

See also in sourсe #XX -- [ , ]

See also in sourсe #XX -- [ ]

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