Cerium, organo- compounds

Ho, D., Corrosion Inhibition Effectiveness of Green Cerinm-organo Compounds Cerium Salicylate and Cerium Di-butyl Phosphate on AA2024 T3 in Both Aqueous and Epoxy Coating Environments, in Materials Engineering. 2007, Monash University Melbourne. 

Boussie, T.R., Eisenberg, D.C., Rigsbee, J. et al. (1991) Structures of organo-f-element compounds differing in the oxidation state of the central metal crystal structures of bis([8]annulene) complexes of cerium(lV), ytterbium(III), and uranium(III). Organometallics, 10, 1922. 

Organolanthanide(III) compounds form the bulk of all the known organo-lanthanides. However, in addition to the + 3 oxidation state, the + 2 oxidation state is chemically accessible for samarium, europium and ytterbium (an organocerium(II) [1] and an organoneodynium(II) [2] complex have also been reported but not structurally confirmed) and the +4 oxidation state is accessible for cerium. A few organolanthanide(O) compounds are also known,... 

USE OF CERIUM(III) CHLORIDE IN THE REACTIONS OF CARBONYL COMPOUNDS WITH ORGANO-LITHIUMS OR GRIGNARD REAGENTS FOR THE SUPPRESSION OF ABNORMAL REACTIONS 1-BUTYL-1,2,3,4-TETRAHYDRO-1 -NAPHTHOL... 

Reviews of carbanionic reactions in synthesis have addressed the use of organo-cerium compounds and ketone formation by reactions of acyl chlorides with organometallic reagents. ... 

PO can be made degradable by means of additives. The types of additives include aromatic ketones (benzo-phenone and substituted benzophenones [47], qui-none), aromatic amines (trisphenylamine), polycyclic aromatic hydrocarbons (anthracene, certain dyes such as xanthene dyes), or transition metal organic compounds. The transition metal compounds of Fe, Co, Ni, Cr, Mn are widely used. Organo-soluble acetyl acetonates of many transition metals are photooxidants and transition metal carboxylates are also thermal pro-oxidants. Co acetylacetonate appears to be an effective catalyst for chemical degradation of PP in the marine environment. The preferred photoactivator system is ferric dibutyldithiocarbamate with a concentration range of 0.01. 1%. Scott has patented the use of organometallic compounds hke iron (ferric) dibutyldithiocarbamate or Ni-dibutyl-dithiocarbamate [48]. Cerium carboxylate [49] and carbon black are also used in such materials [50]. 

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