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Centrifugal distortion symmetric rotors

When the effects of centrifugal distortion are included the term values of a prolate symmetric rotor are given by... [Pg.114]

Kivelson14 has given a treatment of the distortion by the barrier forces and centrifugal effects. This has been applied phenomenologically to CH3SiH3 (a coaxial symmetric rotor) to fit the set of / = 0 to 1 transitions associated with the first few torsional states. One of the parameters involves the barrier height, which was thereby determined. [Pg.381]

The evaluation of centrifugal distortion in asymmetric rotors is considerably more complex than for linear or symmetric tops, and because of the nature of the spectmm, particularly large distortion shifts (say 10(X) MHz or larger) can be observed. A first-order treatment of the P distortion effects gives, for the energy of a semirigid prolate asymmetric rotor (Z o a),... [Pg.309]

See other pages where Centrifugal distortion symmetric rotors is mentioned: [Pg.116]    [Pg.118]    [Pg.32]    [Pg.115]    [Pg.116]    [Pg.118]    [Pg.432]    [Pg.89]    [Pg.289]    [Pg.292]    [Pg.303]    [Pg.22]   
See also in sourсe #XX -- [ Pg.114 ]

See also in sourсe #XX -- [ Pg.114 ]



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