Cement viscosity

Table 8. ASTM Requirements for Asphalt Cement Viscosity...

Uses Solvent for dyes and resins preparation of furfuryl esters furan polymers solvent for textile printing manufacturing wetting agents and resins penetrant flavoring corrosion-resistant sealants and cements viscosity reducer for viscous epoxy resins. 

Barralet JE, Grover LM, Ghureck U. Ionic modification of calcium phosphate cement viscosity. Part II h3q)odemiic injection and strength improvement of brushite cement. Biomaterials. 2004 May 25(11) 2197-203. 

The industrial value of furfuryl alcohol is a consequence of its low viscosity, high reactivity, and the outstanding chemical, mechanical, and thermal properties of its polymers, corrosion resistance, nonburning, low smoke emission, and exceUent char formation. The reactivity profile of furfuryl alcohol and resins is such that final curing can take place at ambient temperature with strong acids or at elevated temperature with latent acids. Major markets for furfuryl alcohol resins include the production of cores and molds for casting metals, corrosion-resistant fiber-reinforced plastics (FRPs), binders for refractories and corrosion-resistant cements and mortars. 

Polyacrylamides are used in many other oilfield appUcations. These include cement additives for fluid loss control in well cementing operations (127), viscosity control additives for drilling muds (128), and fracturing fluids (129). Copolymers [40623-73-2] of acrylamide and acrylamidomethylpropanesulfonic acid do not degrade with the high concentrations of acids used in acid fracturing. 

Welan has similar properties to xanthan gum except that it has increased viscosity at low shear rates and improved thermal stabiUty and compatibihty with calcium at alkaline pH (90). The increased thermal stabiUty has led to its use as a drilling mud viscosifter especially for high temperature weUs. The excellent compatibihty with calcium at high pH has resulted in its use in a variety of specialized cement and concrete appHcations. 

Deflocculation and Slurry Thinning. Sihcates are used as deflocculants, ie, agents that maintain high sohds slurry viscosities at increased sohds concentrations. Soluble sihcates suppress the formation of ordered stmctures within clay slurries that creates resistance to viscous flow within the various sytems. Laboratory trials are necessary, because the complexity of the systems precludes the use of a universal deflocculant. Sihcates are employed in thinning of limestone or clay slurries used in the wet-process manufacture of cements and bricks, clay refining, and petroleum drilling muds (see also... 

Sulfur as an Additive for Asphalt. Sulfur-extended asphalt (SEA) binders are formulated by replacing some of the asphalt cement (AC) in conventional binders with sulfur. Binders that have sulfur asphalt weight ratios as high as 50 50 have been used, but most binders contain about 30 wt % sulfur. Greater latitude in design is possible for SEA paving materials, which are three-component systems, whereas conventional asphalt paving materials are two-component systems. Introduction of sulfur can provide some substantial benefits. At temperatures above 130°C, SEA binders have lower viscosities than conventional asphalt. The lower viscosity enables the plant to produce and compact the mix at lower temperatures than with conventional... 

Specifications for paving asphalt cements usually include five grades differing in either viscosity or penetration level at 60 °C (Table 8) (ASTM D496). Susceptibihty of viscosity to temperature is usually controlled in asphalt cement by viscosity limits at a higher temperature such as 135 °C and a penetration or viscosity limit at a lower temperature such as 25 °C. 

If straight-mn asphalts are reduced to a hardness below 300 penetration (30 mm), they are termed asphalt cements. For hot-mix paving, either the AC-10 viscosity grade or the next harder AC-20 grade is commonly specified. 

Concrete, Mortar, and Plaster. Citric acid and citrate salts are used as admixtures in concrete, mortar, and plaster formulations to retard setting times and reduce the amount of water requited to make a workable mixture (172—180). The citrate ion slows the hydration of Portland cement and acts as a dispersant, reducing the viscosity of the system (181). At levels below 0.1%, citrates accelerate the setting rate while at 0.2—0.4% the set rate is retarded. High early strength and improved frost resistance have been reported when adding citrate to concrete, mortar, and plaster. 

An appHcation where latex paints show outstanding performance is over masonry such as stucco or ciader block constmction. This performance results from saponification resistance ia the preseace of the alkaH from the cement. Furthermore because masoary surfaces are porous, having both small and large pores, the low viscosity external phase of a latex paint can penetrate rapidly iato the small pores, causiag a rapid iacrease ia the viscosity of the remaining paiat. The bulk paiat, ia turn, sinks iato the larger holes more slowly than a solution-based paint. Thus less latex paint is required to cover the same surface area as compared to alkyd paints. 

During World War II, polychloroprene was chosen as a replacement for natural rubber because of its availability. Two copolymers of chloroprene and sulphur which contain thiuram disulphide were available (Neoprene GN and CG). One of the first successful applications of these polychloroprene adhesives was for temporary and permanent sole attachment in the shoe industry. However, these polychloroprene cements show a decrease in viscosity on ageing and a black discolouration appears during storage in steel drums. Discolouration was produced by trace amounts of hydrochloric acid produced by oxidation of polychloroprene... 

There are 16 grades of DuPont neoprene alone. They vary in crystallization rate and potential, viscosity, molecular weight, additive content, and other properties ([216], pp. 284-306). Selection of the right materials requires sophisticated knowledge of both the neoprenes and the phenolic additives. Guggenberger provides a good overview of this situation and some basic formulation information ([216], pp. 284-306). She also provides a prototype formula for a heat-resistant contact cement as shown in the Table 18 ([216], source Table 10, p. 293). 

With this type of fluid the viscosity decreases as the shear strain increases, typical cases being mud and liquid cement. 

Large Scale Rubber Cement High Viscosity Tw o-Phase Flow Test Report, DIERS/AIChE, 1986, 114 pages. 

DlatomaceOUS Earth. Diatomaceous earth has a lower specific gravity than bentonite. Like bentonite this additive also requires additional water to be added to the slurry. This additive will affect the slurry properties similar to the addition of bentonite. However, it will not increase the viscosity as bentonite will do. Diatomaceous earth concentrations as high as 40% by weight of cement have been used. This additive is more expensive than bentonite. 

Examples of commonly used viscosity control additives are calcium ligno-sulfonate, sodium chloride and some long-chain polymers. These additives also act as accelerators or retarders so care must be taken in designing the cement slurry with these materials. 

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