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Carbopalladation intra-intermolecular reactions

Grigg and Xu have developed a variety of so-called queuing cascades involving allenes. The intra-intermolecular carbopalladation sequence of the <9-iodo-A-methyl-A -(methylallyl)aniline 142 and 1,1-dimethylallene 143 with subsequent / -dehydropalladation leads to the 1,3-dienyl-substituted indole derivative 144, which is immediately trapped by an added dienophile (e.g., A-methylmaleimide) in a Diels-Alder reaction to yield 145 (Scheme 37)7 ... [Pg.327]

See other pages where Carbopalladation intra-intermolecular reactions is mentioned: [Pg.324]    [Pg.76]    [Pg.86]    [Pg.183]    [Pg.1379]    [Pg.1551]    [Pg.568]    [Pg.1551]   
See also in sourсe #XX -- [ Pg.1416 , Pg.1417 , Pg.1418 , Pg.1419 , Pg.1420 , Pg.1421 , Pg.1422 ]



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Carbopalladations

Intermolecular carbopalladation

Intra-intermolecular reaction

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