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Carbonyls, metal bridging-terminal carbonyl exchange

The phenomenon of bridge-terminal carbonyl exchange can occur in any dimetal system that can exist in CO-bridged and metal-metal bonded forms, such as COjfCO), ... [Pg.141]

From the values of T,M and B calculated in this way we may note that for both iron and cobalt M 0.68 T and that B 0.5 T. The latter approximation is intuitively consistent with the observations22 of bridge-terminal exchange of coordinated CO. If we now assume that these empirical approximations apply to other polynuclear carbonyls, it is possible to extract the T and M- values for metals other than iron and cobalt, despite the limited AHo data which are available. [Pg.80]

See other pages where Carbonyls, metal bridging-terminal carbonyl exchange is mentioned: [Pg.325]    [Pg.172]    [Pg.330]    [Pg.361]    [Pg.150]    [Pg.269]    [Pg.899]    [Pg.90]    [Pg.261]    [Pg.3956]    [Pg.3956]    [Pg.311]    [Pg.887]    [Pg.6]    [Pg.180]    [Pg.727]    [Pg.3955]    [Pg.312]    [Pg.324]    [Pg.333]    [Pg.346]    [Pg.6]    [Pg.360]    [Pg.99]    [Pg.100]    [Pg.158]    [Pg.431]    [Pg.148]    [Pg.902]    [Pg.437]    [Pg.445]    [Pg.675]    [Pg.190]    [Pg.321]    [Pg.223]    [Pg.226]    [Pg.235]    [Pg.323]    [Pg.140]    [Pg.181]    [Pg.301]    [Pg.156]    [Pg.713]    [Pg.575]    [Pg.1007]    [Pg.193]    [Pg.360]    [Pg.371]   
See also in sourсe #XX -- [ Pg.264 ]



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Bridge-terminal carbonyl exchange

Carbonyls, metal Bridging

Metal bridged

Metal carbonyls bridged

Metallic termination

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